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Modification of X-ray excited photoelectron and C KVV Auger spectra during radiative carbonization of poly(vinylidene fluoride)
dc.contributor.author | Chebotaryov, S.S. | |
dc.contributor.author | Volegov, A.A. | |
dc.contributor.author | Pesin, L.A. | |
dc.contributor.author | Evsyukov, S.E. | |
dc.contributor.author | Moskvina, N.A. | |
dc.contributor.author | Gribov, I.V. | |
dc.contributor.author | Kuznetsov, V.L. | |
dc.contributor.author | Песин, Леонид Абрамович | |
dc.date.accessioned | 2015-07-06T06:15:29Z | |
dc.date.available | 2015-07-06T06:15:29Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 1386-9477 | |
dc.identifier.uri | http://elib.cspu.ru/xmlui/handle/123456789/676 | |
dc.description.abstract | Modifications of the photoelectron and C KVV Auger spectra during the long-term surface degradation of partially crystalline PVDF under simultaneous soft X-ray and electron followed by ion irradiation are reported. Deep radiative carbonization brings about the formation of carbynoid structures (chain-like carbon) in the surface, while the number of interchain cross-links is insignificant. As a result, the shape of the electron emission spectra of carbon in the carbonized sample essentially differs from that of graphite and PVDF. The ion bombardment of the carbonized sample destroys one-dimensional structure due to the formation of cross-links. Thus, carbon atoms transit into sp2-hybrid state and, therefore, the photoelectron and Auger spectra show features characteristic for microcrystalline graphite | ru_RU |
dc.language.iso | en | ru_RU |
dc.subject | XPS | ru_RU |
dc.subject | C KVV Auger spectra | ru_RU |
dc.subject | PVDF | ru_RU |
dc.subject | Carbynoid structures | ru_RU |
dc.subject | Relative carbonization | ru_RU |
dc.title | Modification of X-ray excited photoelectron and C KVV Auger spectra during radiative carbonization of poly(vinylidene fluoride) | ru_RU |
dc.title.alternative | / S.S. Chebotaryov, A.A. Volegov, L.A. Pesin, S.E. Evsyukov, N.A. Moskvina, I.V. Gribov, V.L. Kuznetsov // Physica. - 2007. - V. 36, issue 2. - P. 184–189 | ru_RU |
dc.type | Article | ru_RU |