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Kinetics of PVDF film degradation under electron bombardment
| dc.contributor.author | Pesin, L.A. | |
| dc.contributor.author | Morilova, V.M. | |
| dc.contributor.author | Zherebtsov, D.A. | |
| dc.contributor.author | Evsyukov, S.E. | |
| dc.contributor.author | Песин, Леонид Абрамович | |
| dc.date.accessioned | 2015-07-03T07:37:06Z | |
| dc.date.available | 2015-07-03T07:37:06Z | |
| dc.date.issued | 2013 | |
| dc.identifier.issn | 0141-3910 | |
| dc.identifier.uri | http://elib.cspu.ru/xmlui/handle/123456789/675 | |
| dc.description.abstract | A dose effect of high-energy (20 keV) electron irradiation on the chemical composition of PVDF films has been revealed using a scanning electron microscope Jeol JSM-7001F equipped with an X-ray fluorescence spectrometer Oxford INCA X-max 80. All the experimental series have demonstrated similar decreasing dependence of relative atomic fluorine content (F/C) upon the electron irradiation dose. The final nonzero F/C ratio can be explained in terms of primary defects in the original PVDF and secondary ones arising during irradiation. In general a defluorination process is consistent to a Le Moël model of PVDF degradation and can be satisfactorily described with a third-order kinetic equation, parameters of which depend on the type of a PVDF film. | ru_RU |
| dc.language.iso | en | ru_RU |
| dc.subject | Poly(vinylidene fluoride) (PVDF) | ru_RU |
| dc.subject | Scanning electron microscopy (SEM) | ru_RU |
| dc.subject | Defluorination | ru_RU |
| dc.subject | Kinetics | ru_RU |
| dc.subject | Поливинилиденфторид (ПВДФ) | ru_RU |
| dc.title | Kinetics of PVDF film degradation under electron bombardment | ru_RU |
| dc.title.alternative | / L.A. Pesin, V.M. Morilova, D.A. Zherebtsov, S.E. Evsyukov // Polymer Degradation and Stability. - 2013. - V.98, Issue 2. - P. 666-670 | ru_RU |
| dc.type | Article | ru_RU |